Goku has no chance without ki. Even with Ki he can barely hold his own against these two. He gets distant third.
Superman vs. Invincible is a lot more interesting.
Superman is stronger and more durable. He is capable of pulling 66 quintillion tons in canon and can survive a supernova. Invincible can lift a few million tons and can take damage from punches from people around the same strength as him. Though I should note that the last time Invincible lifted anything really heavy it was closer to 300,000 tons. His strength has increased exponentially since then. Which still places him well below Superman unless exponentially means, "Over 1,000,000,000 times stronger. (And even that is still just in the hundreds of trillions.)
Speed I'm giving to invincible. Superman won't be too much slower, but Invincible can fly to Alpha Centauri in a week, equaling out to 250 times the speed of light. Superman can fly nearly that fast if he needs to, but not quite.
As for martial skill: remember, Superman is the master of several martial arts and being trained by multiple masters, he also has quite a bit of training battling people as strong or stronger than he is. Invincible lacks this experience, so I would put them as about even with Invincible perhaps being a little better.
Furthermore, Superman has a wider range of powers. I'm not talking about heat vision either. Things like superhearing and telescopic vision which let him find his opponents faster, etc. Also, if he needs to get stronger he can sun-dip to gain more power.
Now who would win. Honestly I see this going like the Mongul vs. Wonder Woman fight in the comic the Man who has everything. Wonder Woman is faster and more agile, but in the end Mongul's strength and invincibility overwhelm her. In this fight Invincible will land punch after punch and kick after kick, yet Superman will be almost unharmed from them. Invincible could land a thousand blows before Superman manages one. But that one blow is all that Superman needs to end the fight.
End winner: Superman.