I don't think there is a certain major to educate being a CEO. According to the dictionary, "CEO" means "chief executive officer." Although higher education is not a requirement to be a CEO, many CEOs have higher educational background from various professions. Some CEOs don't even have higher educations, like Steve Jobs of Apple Inc. If you are in high school right now, it is important to find what you are good at what you like to do rather than deciding your major.