Complete the following reactions and name the product that forms. If no reaction occurs, write NR.?

1.) 1,4-cyclohexadiene + KMnO4 --->

2.) 4-methylcyclohexene + KMnO4 --->

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  • trikha
    Lv 5
    1 decade ago
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    It is assumed that hot alkaline KMnO4 is being used. 1,4-Cyclohexadiene on reaction with KMnO4 will break down to a dicarboxylic acid prop-1,3-dioic acid (malonic acid). Malonic acid readily losses CO2 to give acetic acid.

    HO.CO. CH2.CO.OH ---------> CO2 + CH3.COOH

    4-Methylcyclohexene will give a 1,6-dicarboxylic acid. The breakdown of the molecule wil be at C1-C2 double bond. The product will be 3-methylhex-1,6-dioic acid.

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