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Given the redox reaction: Sn + HNO3 --> SnO2 + NO2+ H2O, identify the following: (see details)?

a.) Identify the substance oxidized and the substance reduced.

b.) Identify the oxidizing and reducing agents.

c.) Identify the oxidation and reduction half-reactions and determine the number of electrons lost and gained.

d.) Please balance the equation.

Thanks a lot!

Update:

If possible, please provide the solution. Thanks!

2 Answers

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  • 1 decade ago
    Favorite Answer

    Sn in Sn: Oxid State 0

    Sn in SnO2: Oxid State +4 (since O is -2 and there are 2 of them)

    During oxidation, oxidation number increases, so Sn is being oxidised.

    N in HNO3: +5 (since H is +1 and O is -2 and there are 3 O's)

    N in NO2: +4 (since O is -2 and there are 2 O's)

    During reduction, oxidation number decreases, so N is being reduced.

    b) The Sn is being oxidised by the HNO3, so the HNO3 is the oxidising agent.

    The N is being reduced by the Sn, so the Sn is the reducing agent.

    c) Sn + 2H2O --> SnO2 + 4H+ + 4e

    NO3- + 2H+ + e --> NO2 + H2O

    The Sn loses 4e's (0 to +4) and the N gains an e (+5 to +4)

    d) In a redox reaction, as many electrons are lost as gained. So the second half-equation needs to be multiplied by 4

    Sn + 2H2O --> SnO2 + 4H+ + 4e

    4NO3- + 8H+ + 4e --> 4NO2 + 4H2O

    Summing up, and noticing the 4e on right cancel 4e on left, 4 of the H+ on the left cancel out the 4H+ on the right (leaving 4H+ from 8H+ on the left), and 2 H2O on the left cancel out 2 of the H2O on the right (leaving 2 from 4 H2O on the right)

    Sn + 4NO3- + 4H+ --> SnO2 + 4NO2 + 2H2O

    So

    Sn + 4HNO3 --> SnO2 + 4NO2 + 2H2O

  • 4 years ago

    Sn Hno3

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