Is it possible to straighten your hair with a curling iron? If so, how do you do that?

The curling iron I have is a Vidal Sassoon model vs 101. Don't know if that helps, but I thought I'd let you all know anyway.

My hair is blonde and goes about an inch below my eyes on the eyes, down to the point of my nose in the front, & 2 inches long in the back. AKA it's EMO hair.
Update: Yes, i do know that a curling hair is for curling your hair and not straightening it. I'd use a straightener but I don't have the money to purchase one.
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