Jovovich married actor Shawn Andrews (played Pickford) in October of 1992, while filming Dazed and Confused together; the marriage was annulled by her mother a month later. She married The Fifth Element director Luc Besson in 1997, but the two divorced in 1999. Jovovich also dated Red Hot Chili Peppers guitarist John Frusciante for several months in 2000 and was linked to actor Stephen Dorff. She also had a relationship with Jamiroquai ex-bassist Stuart Zender, during which time they both lived in London. Most recently she has appeared in public with Japanese soccer star Hidetoshi Nakata, but is purported to be engaged to writer/director Paul W. S. Anderson. No date has been set.
Jovovich is also planning to publish her private diaries as an autobiography. Jovovich says, "I've been keeping a diary ever since I was a little girl. I've written about all the places I've been to and all the mad things that I've done, so it would be good to get it all into a book - like an autobiography, but with more of a diary feel to it. I'm not sure how interested anyone would be in publishing it, or reading it, for that matter."
Jovovich is a polyglot - she fluently speaks Russian, French, English and Serbian (possibly to a lesser extent).
